BARBIER-TYPE CARBONYL-ALLYLATION WITH ALLYL COMPOUNDS AND SNCL2 IN THE PRESENCE OF PDCL2[PPH2(M-C6H4SO3NA)](2) UNDER 2-PHASE CONDITIONS

Authors
Citation
T. Okano et al., BARBIER-TYPE CARBONYL-ALLYLATION WITH ALLYL COMPOUNDS AND SNCL2 IN THE PRESENCE OF PDCL2[PPH2(M-C6H4SO3NA)](2) UNDER 2-PHASE CONDITIONS, Chemistry Letters, (1), 1998, pp. 5-6
Citations number
14
Categorie Soggetti
Chemistry
Journal title
ISSN journal
03667022
Issue
1
Year of publication
1998
Pages
5 - 6
Database
ISI
SICI code
0366-7022(1998):1<5:BCWACA>2.0.ZU;2-7
Abstract
The hydrophilic palladium complex efficiently catalyzes the allylation of carbonyl compounds with allyl chlorides or allyl alcohols and SnCl 2 under aqueous-organic biphase conditions, which allow us easily to s eparate the product and to recover the organic solvent from the reacti on mixture.