TETRALKYLAMMONIUM PERMANGANATE EPOXIDATION OF AN UNREACTIVE DOUBLE-BOND BY AN INTRAMOLECULAR OXYGEN-ATOM TRANSFER PROCESS

Authors
CAYCHO JR GARCIATELLADO F DEARMAS P MARREROTELLADO JJ
Citation
Jr. Caycho et al., TETRALKYLAMMONIUM PERMANGANATE EPOXIDATION OF AN UNREACTIVE DOUBLE-BOND BY AN INTRAMOLECULAR OXYGEN-ATOM TRANSFER PROCESS, Chemistry Letters, (1), 1998, pp. 25-26
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
1
Year of publication
1998
Pages
25 - 26
Database
ISI
SICI code
0366-7022(1998):1<25:TPEOAU>2.0.ZU;2-3
Abstract
The ammonium permanganate oxidation of a tricyclic, rigid diene gives the mono- dihydroxylated compound together with the diol- epoxide deri vative. The epoxidation involves an intramolecular oxygen-atom transfe r p rocess from the anchored manganese (V) diester to the second doubl e bond.