THERMAL-REACTION OF THYL(HYDRIDO)((2-PHOSPHINOETHYL)SILYL)IRIDIUM(III) COMPLEX - FORMATION OF A ((2-PHOSPHINOETHYL)SILYL)(ETHENE)IRIDIUM COMPLEX

Authors
OKAZAKI M TOBITA H OGINO H
Citation
M. Okazaki et al., THERMAL-REACTION OF THYL(HYDRIDO)((2-PHOSPHINOETHYL)SILYL)IRIDIUM(III) COMPLEX - FORMATION OF A ((2-PHOSPHINOETHYL)SILYL)(ETHENE)IRIDIUM COMPLEX, Chemistry Letters, (1), 1998, pp. 69-70
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
1
Year of publication
1998
Pages
69 - 70
Database
ISI
SICI code
0366-7022(1998):1<69:TOT>2.0.ZU;2-4
Abstract
Thermolysis of LnIr(C2H5)(H) [L-n = {eta(2)-Me2Si(CH2)(2)PPh2}(PMe3)(2 )] led to the clean formation of a 1 : 1 mixture of ethene complex LnI r(C2H4) and dihydrido complex LnIr(H)(2). The former product is proved to be an efficient precursor of an unsaturated silyliridium(I) specie s through dissociation of ethene.