NEAR-INFRARED HIGH-RESOLUTION DIODE-LASER SPECTRUM OF THE CH2(B)OVER-TILDE(1)B(1)[-(A)OVER-TILDE(1)A(1) TRANSITION

A new diode laser-based spectrometer operating at wavelengths close to 1 mu m has been constructed for transient absorption measurements in the gas phase. Using a dual beam detection system for noise cancellati on, the minimum detectable absorption was found to be 1 x 10(-4) in 0. 5 mu sec. The sensitivity of the instrument is illustrated by the obse rvation of previously undetected spectra of singlet methylene (CH2) be tween 9780 and 10070 cm(-1). Rovibronic transitions involving two K-a = 1 levels, nominally associated with v(2)(bent) = 1 and 2, in the upp er, <(b)over tilde B-1(1)> state have been assigned. These levels are the lowest so far observed for methylene in this electronic state and their positions provide new information on the shape of the bending po tential for the molecule at energies approaching that at which the two lowest singlet states (<(a)over tilde (1)A(1)> and <(b)over tilde B-1 (1)>) of the molecule become degenerate at the linear configuration. ( C) 1998 Academic Press.