Gs. Okram et al., POSSIBLE COMPETITIVE ELECTRON-LIKE AND HOLE-LIKE CONDUCTION IN THE REVIVED ND1.82CE0.18CUOY SUPERCONDUCTORS, Physica. C, Superconductivity, 277(1-2), 1997, pp. 19-23
Thermoelectric power (S) studies on the nominally electron-doped Nd1.8
2-zSrzCe0.18CuOy (NSCCO) superconductor system in the temperature rang
e 35 K to 250 K are reported here, S of the reduced z = 0.09 sample ha
s negative sign, indicating electron conduction, and has small magnitu
de, showing high metallicity. The sign of S for the z = 0.18 sample ho
wever shows a cross-over below 75 K, from negative to positive, confli
cting perhaps with electronic conduction, This sample on oxygenation e
xhibits broadened positive peak and apparently gets carrier concentrat
ion enhanced. There is seemingly a competition between electron and ho
le-like conduction in these co-doped compounds also.