ELECTRIC-DIPOLE POLARIZABILITY OF AS-4, A CHALLENGING PROBLEM FOR BOTH EXPERIMENT AND THEORY

Authors
HOHM U GOEBEL D KARAMANIS P MAROULIS G
Citation
U. Hohm et al., ELECTRIC-DIPOLE POLARIZABILITY OF AS-4, A CHALLENGING PROBLEM FOR BOTH EXPERIMENT AND THEORY, The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 102(8), 1998, pp. 1237-1240
Citations number
34
Categorie Soggetti
Chemistry Physical
Journal title
The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory → ACNP
ISSN journal
10895639
Volume
102
Issue
8
Year of publication
1998
Pages
1237 - 1240
Database
ISI
SICI code
1089-5639(1998)102:8<1237:EPOAAC>2.0.ZU;2-F
Abstract
An experimental value of 116.7 +/- 1.1 e(2)a(0)(2)E(h)(-1) for the Sta tic dipole polarizability of As-4 is deduced from the analysis of refr activity measurements in arsenic vapor. This is in close agreement wit h the theoretical result of 119.5 +/- 3.6 e(2)a(0)(2)E(h)(-1), obtaine d from ab initio finite-field many-body perturbation theory and couple d-cluster calculations.