Adsorption of Sb on a misoriented Si(111) surface is investigated by t
hermodesorption Auger spectroscopy. The spectra reveal that, in the su
bmonolayer range, new adsorption states appear for the vicinal surface
which do not exist for the nominal one. Quenched molecular-dynamics s
imulations, in which Si and Sb are modeled by many-body tight-binding
potentials, allow us to interpret these new states as due to a molecul
ar adsorption at the steps instead of a dissociative one on the terrac
es. (C) 1998 Elsevier Science B.V.