O. Millo et al., RESONANT-TUNNELING THROUGH DISCRETE ELECTRONIC LEVELS OF A C-60 MOLECULE IN THE PRESENCE OF CHARGING EFFECTS, Acta Physica Polonica. A, 93(2), 1998, pp. 431-435
We have conducted tunneling spectroscopy studies for isolated C-60 mol
ecules in the double barrier tunnel junction configuration. The tunnel
ing current-voltage (I-V) and dI/dV vs. V spectra of these molecules e
xhibit rich structures resulting from both resonant tunneling through
the discrete levels and single electron charging effects. In particula
r, we observe degeneracy lifting within the molecular orbitals, probab
ly due to the Jahn-Teller effect and local electric fields. Theoretica
l fits, performed using the ''orthodox'' model for single-electron tun
neling modified to account for the discrete level spectrum of C-60, ag
ree well with our data.