The sublimation of the CdTe(001) surface (greater than or equal to 300
degrees C) was investigated by high-resolution low energy electron di
ffraction (HRLEED). From intensity oscillations of the specular diffra
ction spot as a function of time and energy we deduce a periodic varia
tion of the step density, in agreement with the interpretation of earl
ier reflection high energy electron diffraction (RHEED) data within th
e step density model. However, our quantitative profile analysis shows
that the relative change of the step density is only very small (appr
oximate to 15%). Thus the dominant contribution to the total desorptio
n flux is due to step-flow, but not due to layer-by-layer sublimation.
An important and general consequence is that absolute values of subli
mation rates cannot be determined from intensity oscillation periods a
lone. (C) 1998 Elsevier Science B.V.