SPECULAR REFLECTANCE INFRARED-SPECTRA OF THE MACROCYCLES CYCLAM AND CYCLAMDIONE AND THEIR CU(II) COMPLEXES DEPOSITED ONTO A SMOOTH COPPER SURFACE

Authors
DIAZ G CLAVIJO RE CAMPOSVALLETE MM SAAVEDRA M DIEZ S MUNOZ R
Citation
G. Diaz et al., SPECULAR REFLECTANCE INFRARED-SPECTRA OF THE MACROCYCLES CYCLAM AND CYCLAMDIONE AND THEIR CU(II) COMPLEXES DEPOSITED ONTO A SMOOTH COPPER SURFACE, Vibrational spectroscopy, 15(2), 1997, pp. 201-209
Citations number
26
Journal title
Vibrational spectroscopy → ACNP
ISSN journal
09242031
Volume
15
Issue
2
Year of publication
1997
Pages
201 - 209
Database
ISI
SICI code
0924-2031(1997)15:2<201:SRIOTM>2.0.ZU;2-D
Abstract
An infrared study of the macrocycles cyclam, cyclamdione and its Cu(II ) complexes has been performed. The specular reflectance infrared spec trum was recorded and analyzed for the ligands and complexes deposited onto a smooth copper surface. Several spectral modifications resultin g from the macrocycle-metal surface interaction are interpreted in ter ms of molecular structural changes. An orientation of the ligands and complexes onto the metal surface is proposed. (C) 1997 Elsevier Scienc e B.V.