ANALYSIS OF THE K-SUBBAND STRUCTURE OF THE NU(1)FUNDAMENTAL OF PROPARGYL RADICAL H2CCCH

Authors
YUAN L DESAIN J CURL RF
Citation
L. Yuan et al., ANALYSIS OF THE K-SUBBAND STRUCTURE OF THE NU(1)FUNDAMENTAL OF PROPARGYL RADICAL H2CCCH, Journal of molecular spectroscopy, 187(1), 1998, pp. 102-108
Citations number
20
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
Journal title
Journal of molecular spectroscopy → ACNP
ISSN journal
00222852
Volume
187
Issue
1
Year of publication
1998
Pages
102 - 108
Database
ISI
SICI code
0022-2852(1998)187:1<102:AOTKSO>2.0.ZU;2-1
Abstract
The K-subband structure of the acetylenic CH stretch fundamental. nu(1 ), of propargyl radical, CH2CCH, has been assigned and analyzed. The K = 0, 1-, 1+, 3, 4, 5, and 6 upper state energies totaling 109 levels could be accurately fitted with Watson's fourth-order A-reduced Hamilt onian. The K = 2 subband was perturbed with the level crossing between N = 17 and 18. (C) 1998 Academic Press.