Jh. Lee et al., A SIMPLE GEOMETRICAL MODEL FOR THRESHOLD BEHAVIOR AND MOLECULAR SWITCHING DYNAMICS IN ANTIFERROELECTRIC LIQUID-CRYSTALS, Journal of the Korean Physical Society, 32, 1998, pp. 1089-1092
We have developed a geometrical model for the field induced antiferroe
lectric-ferroelectric (AF-FO) liquid crystal phase transition. The mod
el is based on the electrostatic dipolar interactions between two near
est neighboring dipoles at the molecular ends. The observed temperatur
e dependences of the threshold field, E-th, for the AF-FO transition,
the polarization, P, in the FO phase, the molecular switching are cons
istent with theoretical predictions. A linear relationship between E-t
h and P is found in the region where the molecular tilt remains fairly
constant.