T. Takami et S. Ino, ORGANOMETALLIC MICELLE COMPRISED OF GOLD MULTIPLY TWINNED PARTICLE AND SELF-ASSEMBLED THIOLS, Surface review and letters, 4(6), 1997, pp. 1381-1384
We have demonstrated the method to stabilize gold particles by using t
he technique of self-assembled alkanethiol. Au and S peaks of the X-ra
y spectroscopy show that it consists of Au particle and alkanethiols.
The chemical bond between Au and S is confirmed by the NMR spectrum. T
he typical size of the particle is less than 30 nm, observed by the sc
anning electron microscope. The predicted structure of the thiol-adsor
bed particle is like a micelle, and we have named this particle the or
ganometallic micelle.