E. Brillas et al., DEGRADATION OF 4-CHLOROPHENOL BY ANODIC-OXIDATION, ELECTRO-FENTON, PHOTOELECTRO-FENTON, AND PEROXI-COAGULATION PROCESSES, Journal of the Electrochemical Society, 145(3), 1998, pp. 759-765
Citations number
30
Categorie Soggetti
Electrochemistry,"Materials Science, Coatings & Films
The degradation of 4-chlorophenol in acidic solution of pH similar to
3.5 has been studied by different electrochemical methods involving H2
O2 electrogeneration from an O-2-diffusion cathode. While the solution
is slowly mineralized by anodic oxidation in the presence of H2O2, th
e rate for organic carbon removal increases notably by electro-Fenton,
photoelectro-Fenton, and peroxi-coagulation, where Fe2+ acts as catal
yst to produce oxidizing OH. from electrogenerated H2O2. A complete mi
neralization was only reached in the photoelectro-Fenton process. For
peroxi-coagulation, the removal of organic carbon in solution is mainl
y due to the coagulation of dechlorinated intermediates with the Fe(OH
)(3) precipitate formed. The decay for substrate concentration is fast
er by electro-Fenton and photoelectro-Fenton than by peroxi-coagulatio
n. In all methods, the initial hydroxylated intermediate is 4-chloro-1
,2-dihydroxybenzene, which is further oxidized with loss of chloride i
on to yield maleic and fumaric acids. Fe3+ complexes are produced in t
he processes using iron ions. These complexes are slowly mineralized b
y electro-Fenton and rapidly photodecomposed to CO2 by photoelectro-Fe
nton processes. The apparent current efficiencies for the mineralizati
on processes have been determined. A general pathway for the degradati
on of 4-chlorophenol by the different methods studied is proposed.