PD-FULLERENE COMPLEX FOR SELECTIVE HYDROGENATION OF DEHYDROLINALOOL

Authors
SULMAN EM MATVEEVA VG BASHILOV VV SOKOLOV VI
Citation
Em. Sulman et al., PD-FULLERENE COMPLEX FOR SELECTIVE HYDROGENATION OF DEHYDROLINALOOL, Kinetics and catalysis, 38(2), 1997, pp. 251-252
Citations number
3
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
38
Issue
2
Year of publication
1997
Pages
251 - 252
Database
ISI
SICI code
0023-1584(1997)38:2<251:PCFSHO>2.0.ZU;2-7
Abstract
The Pd phosphine complex with fullerene C-60 (eta(2)-C-60 Pd(PPh3)(2)) (I) is used as the catalyst for homogeneous and heterogeneous hydroge nation of 3,7-dimethylocta-6-en-1-yn-3-ol (dehydrolinalool) (DHL). In all cases, the triple bond of DHL is hydrogenated into the double bond in the presence of the palladium-fullerene complex. The sibunit-suppo rted complex I exhibits the highest catalytic activity, which is by an order of magnitude higher than that of the Pd-sibunit catalyst.