OXIDATIVE-DEGRADATION OF LACTOSE HYDRAZONES TO GALAROSE

Authors
TURJAN J PATOPRSTY V PETRUSOVA M PETRUS L
Citation
J. Turjan et al., OXIDATIVE-DEGRADATION OF LACTOSE HYDRAZONES TO GALAROSE, Chemicke zvesti, 51(6B), 1997, pp. 432-436
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Chemicke zvesti → ACNP
ISSN journal
03666352
Volume
51
Issue
6B
Year of publication
1997
Pages
432 - 436
Database
ISI
SICI code
0366-6352(1997)51:6B<432:OOLHTG>2.0.ZU;2-2
Abstract
Oxidative degradation of lactose 2,5-dichlorophenylhydrazone to galaro se and 2-(2,5-dichlorophenyl)hydrazinecarbaldehyde with hydrogen perox ide was found to give the best results in a weakly acidic medium under catalysis of ammonium heptamolybdate. Of fourteen lactose hydrazones evaluated, the best yields of galarose were obtained with 2,4-, 2,5-, and 3,5-dichlorophenylhydrazones.