The composition of Pt-Rh alloys that co-exist with Rh2O3 in air have b
een identified by experiment at 1273 K. The isothermal sections of the
phase diagram for the ternary system Pt-Rh-O at 973 K and 1273 K have
been computed based on experimentally determined phase relations and
recent thermodynamic measurements on Pt1-XRhX alloys and Rh2O3. The co
mposition dependence of the oxygen partial pressure for the oxidation
of Pt1-XRhX alloys at different temperatures, and temperature for the
oxidation of the alloys in air are computed. The diagrams provide quan
titative information for optimization of the composition of Pt1-XRhX a
lloys for high temperature application in oxidizing atmospheres.