ALLYLATION OF CARBONYL-COMPOUNDS IN THE PRESENCE OF CATALYTIC ELECTROGENERATED ZINC - UNUSUAL REGIOSELECTIVITY WITH A TRIFLUORINATED ANALOGOF PRENYL BROMIDE

Authors
GOSMINI C ROLLIN Y PERICHON J WAKSELMAN C TORDEUX M MARIVAL L
Citation
C. Gosmini et al., ALLYLATION OF CARBONYL-COMPOUNDS IN THE PRESENCE OF CATALYTIC ELECTROGENERATED ZINC - UNUSUAL REGIOSELECTIVITY WITH A TRIFLUORINATED ANALOGOF PRENYL BROMIDE, Tetrahedron, 53(17), 1997, pp. 6027-6034
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
17
Year of publication
1997
Pages
6027 - 6034
Database
ISI
SICI code
0040-4020(1997)53:17<6027:AOCITP>2.0.ZU;2-U
Abstract
A mild and effective method of electrochemical zinc activation based o n the cathodic reduction of a catalytic amount of ZnBr2 in acetonitril e is applied to the coupling of a trifluorinated analog of prenyl brom ide with carbonyl compounds and affords unusual regioselectivity. (C) 1997 Elsevier Science Ltd.