KINETICS OF THE REACTION OF DIMETHYLDIOXIRANE WITH ADAMANTANE IN AN OXYGEN ATMOSPHERE

Authors
KHUSNULLINA DR KAZAKOV DV KABALNOVA NN KHURSAN SL SHERESHOVETS VV
Citation
Dr. Khusnullina et al., KINETICS OF THE REACTION OF DIMETHYLDIOXIRANE WITH ADAMANTANE IN AN OXYGEN ATMOSPHERE, Kinetics and catalysis, 39(1), 1998, pp. 4-7
Citations number
8
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
39
Issue
1
Year of publication
1998
Pages
4 - 7
Database
ISI
SICI code
0023-1584(1998)39:1<4:KOTROD>2.0.ZU;2-2
Abstract
The consumption of dimethyldioxirane (DMDO) is examined by the spectro photometric method with the purpose of studying the kinetics of the re action of DMDO with adamantane (AdH) in an acetone solution at 30-50 d egrees C. The effective first-order rate constants depend on the AdH c oncentration and are independent of the DMDO concentration. The data o btained agree with the radical mechanism of the process. The rate cons tant of dimethyldioxirane decomposition to bis-oxyisopropylidene birad ical is determined.