Kp. Meletov et Vk. Dolganov, CRYSTAL-FIELD INDUCED MIXING OF ELECTRON-STATES IN C-60 CRYSTALS AT HIGH-PRESSURE, Journal of experimental and theoretical physics, 86(1), 1998, pp. 177-181
Optical absorption spectra of thin fullerene (C-60) crystals in the ra
nge 1.7 to 3.8 eV have been measured at T=300 K and at pressures up to
2.5 GPa. The spectrum shifts toward the red with pressure, and the el
ectron absorption intensity is redistributed among its bands. The inte
nsity of the band associated with the lowest direct electron interband
transition monotonically increases with pressure, whereas the intensi
ty of the upper interband feature decreases. Bands related to weak edg
e absorption in the range between 1.7 and 2.2 eV gradually merge with
the band associated with the lowest interband transition, whose intens
ity rises with pressure. A similar redistribution of intensity among e
lectron transition bands has been observed when comparing the spectrum
of an isolated C-60 molecule and that of a C-60 crystal. The results
indicate that the crystal-field induced mixing of electron states is p
resent in solid C-60, and they can be discussed in terms of the Craig-
McClure model, which was suggested to describe crystal-field induced m
ixing of electron states in anthracene and naphthalene molecular cryst
als. (C) 1998 American Institute of Physics.