STUDIES TOWARDS TOTAL SYNTHESIS OF ANTILLATOXIN - INVESTIGATION OF THE INDIUM-MEDIATED ALLYLATION REACTIONS OF CARBONYL-COMPOUNDS WITH BETA-BROMOCROTYLBROMIDE IN WATER

Authors
Citation
Tp. Loh et al., STUDIES TOWARDS TOTAL SYNTHESIS OF ANTILLATOXIN - INVESTIGATION OF THE INDIUM-MEDIATED ALLYLATION REACTIONS OF CARBONYL-COMPOUNDS WITH BETA-BROMOCROTYLBROMIDE IN WATER, Tetrahedron letters, 39(11), 1998, pp. 1453-1456
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
39
Issue
11
Year of publication
1998
Pages
1453 - 1456
Database
ISI
SICI code
0040-4039(1998)39:11<1453:STTSOA>2.0.ZU;2-9
Abstract
Indium mediates the coupling of beta-bromocrotylbromide with carbonyl compounds in saturated ammonium chloride in the presence of lanthanide triflate under sonication to give the corresponding compounds in good yield and moderate to high syn diastereoselectivity. (C) 1998 Elsevie r Science Ltd. All rights reserved.