The superparamagnetic relaxation time of carbon-supported alpha-Fe par
ticles with an average size of 3.0 Mm has been studied over a large te
mperature range by the use of Mossbauer spectroscopy combined with AC
and DC magnetization measurements. It is found that the relaxation tim
e varies with temperature in accordance with Ni el's expression, tau =
tau(0) exp (KV/kT) with tau(0) = (1.0 +/- 0.5) x 10(-10) s and K = (1
.2 +/- 0.2) x 10(5) J m(-3). (C) 1998 Elsevier Science B.V. All rights
reserved.