MAGNETIC AND ELECTRONIC-STATE OF CO IN LACOO3

Authors
OKUDA K KAWAMATA S NAKAHIGASHI K ISHIBASHI H HAYASHI M OHTA H NOJIRI H MOTOKAWA M
Citation
K. Okuda et al., MAGNETIC AND ELECTRONIC-STATE OF CO IN LACOO3, Journal of magnetism and magnetic materials, 177, 1998, pp. 1375-1376
Citations number
3
Categorie Soggetti
Material Science","Physics, Condensed Matter
Journal title
Journal of magnetism and magnetic materials → ACNP
ISSN journal
03048853
Volume
177
Year of publication
1998
Part
2
Pages
1375 - 1376
Database
ISI
SICI code
0304-8853(1998)177:<1375:MAEOCI>2.0.ZU;2-X
Abstract
High-spin state of Co in LaCoO3 was investigated by the X-ray diffract ion (XRD) and submillimeter ESR method. The ESR signals of high-spin s tate Co3+ were found in the frequency range above 150 GHz at temperatu res above 25 K. They were discussed by the thermal activation and the crystal distortion model. The XRD and the maximum entropy method (MEM) analysis revealed the high density of electron distribution along the chain -O-Co-O-. (C) 1998 Elsevier Science B.V. All rights reserved.