SIZE EFFECT ON STRUCTURE AND INFRARED BEHAVIOR IN NANOCRYSTALLINE MAGNESIUM-OXIDE

Authors
YE XS SHA J JIAO ZK ZHANG LD
Citation
Xs. Ye et al., SIZE EFFECT ON STRUCTURE AND INFRARED BEHAVIOR IN NANOCRYSTALLINE MAGNESIUM-OXIDE, Nanostructured materials, 8(7), 1997, pp. 945-951
Citations number
15
Journal title
Nanostructured materials → ACNP
ISSN journal
09659773
Volume
8
Issue
7
Year of publication
1997
Pages
945 - 951
Database
ISI
SICI code
0965-9773(1997)8:7<945:SEOSAI>2.0.ZU;2-U
Abstract
From the results of Fourier Transform infrared (FTIR) spectra and X-ra y Diffraction (XRD), we found that there exists size effect on the str ucture and infrared behavior in nanocrystalline MgO. When the grain si ze decreases, the crystal lattice dilates anisotropically, and the red shift of stretching vibrational mode coexists with the blue shift of the bending vibrational mode. We give a preliminary interpretation to the above abnormal phenomena. (C) 1998 Acta Metallurgica Inc.