Mc. Pham et al., ANODIC-OXIDATION OF 5-AMINO-1,4-NAPHTHOQUINONE (ANQ) AND SYNTHESIS OFA CONDUCTING POLYMER (PANQ), Synthetic metals, 92(3), 1998, pp. 197-205
The electrooxidation of 5-amino-1,4-naphthoquinone (ANQ) at glassy car
bon and Pt electrodes in acetonitrile leads to functionalized polymer
films. Results from different spectroscopic techniques (FT-IR, UV-Vis,
X-ray photoelectron spectroscopy (XPS)) and frontier orbital consider
ations converge to a definition of poly(5-amino-1,4-naphthoquinone) (P
ANQ) structure which is of the polyaniline-type bearing one quinone gr
oup per ANQ moiety. (C) 1998 Elsevier Science S.A.