A NOVEL FORMULA FOR LOCATION OF DOUBLE-BOND IN ALKENYL ACETATES AND ALCOHOLS BASED ON MASS-SPECTRAL DATA OF DIMETHYL DISULFIDE DERIVATIVES

Authors
XIAO JH YUAN G YANG LZ SUN YF WANG XL
Citation
Jh. Xiao et al., A NOVEL FORMULA FOR LOCATION OF DOUBLE-BOND IN ALKENYL ACETATES AND ALCOHOLS BASED ON MASS-SPECTRAL DATA OF DIMETHYL DISULFIDE DERIVATIVES, Chinese journal of chemistry, 15(6), 1997, pp. 534-540
Citations number
16
Journal title
Chinese journal of chemistry → ACNP
ISSN journal
1001604X
Volume
15
Issue
6
Year of publication
1997
Pages
534 - 540
Database
ISI
SICI code
1001-604X(1997)15:6<534:ANFFLO>2.0.ZU;2-9
Abstract
A new formula was presented for locating double bond position in dodec enols, tetradcenols hexadecenols and their acetates, based on mass spe ctral data of dimethyl disulfide derivatives. In this procedure, molec ular ion and base peak ion were utilized as characteristic parameters to identify the positional isomers. The method was tested with mass sp ectra of 25 dimethyl disulfide derivatives of mono-unsaturated acetate s and alcohols, and the original double-bond position in each isomer w as located unambiguously.