T. Fockenberg, AN EXPERIMENTAL-STUDY OF THE PRESSURE-TEMPERATURE STABILITY OF MGMGAL-PUMPELLYITE IN THE SYSTEM MGO-AL2O3-SIO2-H2O, The American mineralogist, 83(3-4), 1998, pp. 220-227
The stability field of MgMgAl-pumpellyite, Mg5Al5Si6O21(OH)(7), was de
termined in the system MgO-Al2O3-SiO2-H2O in reversal experiments at p
ressures between 34 and 100 kbar and temperatures in the range of 597
to 1050 degrees C. Brackets were obtained on five breakdown reactions
(in order of increasing pressure): [GRAPHICS] This phase becomes stabl
e only at pressures of more than 34 kbar and temperatures up to 820 de
grees C. Thus, MgMgAl-pumpellyite may be an H2O-containing phase at de
pths greater than 100 km in the coldest parts of subduction zones.