A NEW METHOD FOR SPIN-SPIN COUPLING PATTERNS ANALYSIS IN HIGH-RESOLUTION NMR-SPECTROSCOPY

Authors
BOURG S NUZILLARD JM
Citation
S. Bourg et Jm. Nuzillard, A NEW METHOD FOR SPIN-SPIN COUPLING PATTERNS ANALYSIS IN HIGH-RESOLUTION NMR-SPECTROSCOPY, Journal de chimie physique et de physico-chimie biologique, 95(2), 1998, pp. 187-191
Citations number
11
Categorie Soggetti
Biology,"Chemistry Physical
Journal title
Journal de chimie physique et de physico-chimie biologique → ACNP
Volume
95
Issue
2
Year of publication
1998
Pages
187 - 191
Database
ISI
SICI code
Abstract
The measurement of scalar coupling constants is a problem of general i mportance in liquid state Nuclear Magnetic Resonance and for which man y solutions have been proposed. A transformation algorithm applied to time domain data was used to achieve this goal. It yields multiplicity as a function of possible J values. The effectiveness of the method i s demonstrated on m-bromonitrobenzene, a molecule whose H-1 NMR spectr um exhibits hard to measure small couplings.