C. Carlotti et al., SIGNAL-TO-NOISE ENHANCEMENT WHEN T-2-NOT-EQUAL-T-1, A NEW INVESTIGATION OF THE PULSE SEQUENCE DEFT, Journal de chimie physique et de physico-chimie biologique, 95(2), 1998, pp. 208-215
Very long experimental times are necessary in order to obtain NMR spec
tra when the observed nuclei present important spin-lattice relaxation
times. DEFT sequence allows for reduction of acquisition time though
increasing the signal to noise ratio. An analytical approach is propos
ed for which optimal conditions of usage has been defined for the spec
ial case of T-2<<T-1. To obtain full maximization it is necessary to u
se linear prediction. At last a 2D exchange experiment using DEFT is p
resented.