QPASS - TOWARDS HIGHER RESOLUTION IN NMR OF HALF-INTEGER QUADRUPOLAR NUCLEI WITH HIGH QUADRUPOLAR COUPLINGS

Authors
MASSIOT D MONTOUILLOUT V FAYON F FLORIAN P BESSADA C
Citation
D. Massiot et al., QPASS - TOWARDS HIGHER RESOLUTION IN NMR OF HALF-INTEGER QUADRUPOLAR NUCLEI WITH HIGH QUADRUPOLAR COUPLINGS, Journal de chimie physique et de physico-chimie biologique, 95(2), 1998, pp. 270-279
Citations number
25
Categorie Soggetti
Biology,"Chemistry Physical
Journal title
Journal de chimie physique et de physico-chimie biologique → ACNP
Volume
95
Issue
2
Year of publication
1998
Pages
270 - 279
Database
ISI
SICI code
Abstract
We explain the newly described QPASS (Quadrupolar Phase Adjusted Spinn ing Sideband) pulse sequence (Massiot et al. 1997) that opens a way fo r obtaining better resolved NMR spectra of half integer quadrupolar nu clei undergoing large second order quadrupolar broadenings like Ga-71. This two dimensional experiment is based on the modulation of each sp inning sideband by its order with nine pi pulses, from which an infini te spinning rate sideband free spectrum can be reconstructed.