A large class of solids, including certain metals and polymers, when s
ubject to significant deformations undergo microstructural changes tha
t engender a response that is distinctly different from that before wh
ich the microstructural changes occurred. Such microstructural changes
usually lead to inelastic response. This paper is devoted to the stud
y of one such microstructural change, attributed to deformation induce
d twinning. From a macroscopic point of view, within the framework of
a general continuum theory originally developed for polymers by Rajago
pal and Wineman [1] and modified appropriately to model crystalline ma
terials by Rajagopal and Srinivasa [2,3]. In this paper, we elucidate
the intricate interplay between the storage and dissipation of energy
due to deformation and their influence on the propagation and arrest o
f twinning. The onset of twinning is determined purely by energy consi
derations. We show that the entire constitutive structure of the mater
ial can be reduced to the specification of three scalar functions to m
odel ''quasi equilibriated twinning'': the Helmholtz free energy poten
tial psi, the rate of dissipation Function xi and the activation funct
ion g. For the dynamical case (when inertial effects cannot be ignored
), an additional constitutive function for the kinetic energy associat
ed with the process of twinning must be specified. (C) 1998 Acta Metal
lurgica Inc.