We have applied the phenomenological model of diffused interfaces, dev
eloped originally to describe the Fe growth on Bi2Sr2CaCu2O8, to inter
pret quantitatively the core photoemission spectra of two reactive int
erfaces, namely Cr and Ge on Bi2Sr2CaCu2O8. At room temperature the in
terfaces with Fe and Cr have the same kinetics of growth suggesting si
milar adatom condensation, while the semiconductor-superconductor inte
rface grows layer-by-layer according to the Franck-van der Merwe kinet
ics. Differences in the parameters of the model resulting from the sim
ultaneous fit of the core-level decays are related to differences in t
he microscopic processes occurring during the growth.