EFFECTIVE SHAPE AND DYNAMICS OF CHLOROPHYLL-A IN A NEMATIC LIQUID-CRYSTAL

The ordering matrix and the three rotational diffusion tensor componen ts of chlorophyll a dissolved in the nematic liquid crystal ZLI-1167 h ave been determined at various temperatures employing a time-dependent fluorescence depolarization technique, The axis normal to the porphyr in ring is aligned on average perpendicular to the director and exhibi ts the slowest tumbling with respect to the director. The phytyl chain tends to be aligned with the director, and its overall spinning is th e fastest.