SOLID-SOLID CATALYSIS BY ULTRAFINE CRYSTALLITES OF HETEROPOLY COMPOUND FOR PINACOL REARRANGEMENT

Authors
TOYOSHI Y NAKATO T TAMURA R TAKAHASHI H TSUE H HIRAO K OKUHARA T
Citation
Y. Toyoshi et al., SOLID-SOLID CATALYSIS BY ULTRAFINE CRYSTALLITES OF HETEROPOLY COMPOUND FOR PINACOL REARRANGEMENT, Chemistry Letters, (2), 1998, pp. 135-136
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
2
Year of publication
1998
Pages
135 - 136
Database
ISI
SICI code
0366-7022(1998):2<135:SCBUCO>2.0.ZU;2-9
Abstract
Cs2.5H0.5PW12O40 consisting of ultrafine crystallites efficiently cata lyzes pinacol rearrangement of 1,1,2-triphenyl-1,2-ethanediol at room temperature in solid-solid reaction system, giving the corresponding a ldehyde selectively, while p-toluenesulfonic acid, H-ZSM-5, HY, SiO2-A l2O3, SO42-/ZrO2 and Nb2O5 . nH(2)O were inactive. The activity of Cs2 .5H0.5PW12O40 in the solid-solid reaction was higher than that in soli d-liquid (CHCl3) system.