SYNTHESIS OF A SILYLENE-BRIDGED AND HYDRIDE-BRIDGED RE-W HETEROBIMETALLIC COMPLEX AND ITS PHOTOLYSIS TO FORM NOVEL SILENYL-BRIDGED HETEROBIMETALLIC COMPLEXES

Authors
SAKABA H ISHIDA K HORINO H
Citation
H. Sakaba et al., SYNTHESIS OF A SILYLENE-BRIDGED AND HYDRIDE-BRIDGED RE-W HETEROBIMETALLIC COMPLEX AND ITS PHOTOLYSIS TO FORM NOVEL SILENYL-BRIDGED HETEROBIMETALLIC COMPLEXES, Chemistry Letters, (2), 1998, pp. 149-150
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
2
Year of publication
1998
Pages
149 - 150
Database
ISI
SICI code
0366-7022(1998):2<149:SOASAH>2.0.ZU;2-X
Abstract
The reaction of cis-CpW(CO)(2)(MeCN)Me (1) with Cp*(CO)(2)Re(H)SiMe2H (2) gave the silylene- and hydridebridged heterobimetallic complex Cp (CO)(2)W(mu-SiMe2)(mu-H)Re(CO)(2)Cp* (3). Photolysis of 3 produced an isomeric mixture of novel silenyl-bridged heterobimetallic complexes Cp(CO)(2)HW(mu-eta(1), eta(2)-SiME CH2)ReH(CO)(2)Cp* (4).