NOVEL PERFLUOROCYCLOHEXYLATION WITH BIS(PERFLUOROCYCLOHEXANE CARBONYL) PEROXIDE

Authors
SAWADA H KURACHI M KAWASE T TAKISHITA K TANEDANI T AOSHIMA K
Citation
H. Sawada et al., NOVEL PERFLUOROCYCLOHEXYLATION WITH BIS(PERFLUOROCYCLOHEXANE CARBONYL) PEROXIDE, Chemistry Letters, (2), 1998, pp. 153-154
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
2
Year of publication
1998
Pages
153 - 154
Database
ISI
SICI code
0366-7022(1998):2<153:NPWBC>2.0.ZU;2-8
Abstract
A new bis(perfluorocyclohexane carbonyl) peroxide was prepared by the reaction of the corresponding acyl fluoride and hydrogen peroxide. Thi s peroxide was applicable for the direct introduction of perfluorocycl ohexyl group into various organic molecules such as acrylic acid oligo mer, benzene and polystyrene; in particular interest, not only equator ial but also axial conformational isomers were isolated in phenylperfl uorocyclohexane thus obtained.