RHODIUM-CATALYZED SI-F EXCHANGE-REACTION BETWEEN FLUOROBENZENES AND ADISILANE - CATALYTIC REACTION INVOLVING CLEAVAGE OF C-F BONDS

Authors
ISHII Y CHATANI N YORIMITSU S MURAI S
Citation
Y. Ishii et al., RHODIUM-CATALYZED SI-F EXCHANGE-REACTION BETWEEN FLUOROBENZENES AND ADISILANE - CATALYTIC REACTION INVOLVING CLEAVAGE OF C-F BONDS, Chemistry Letters, (2), 1998, pp. 157-158
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
2
Year of publication
1998
Pages
157 - 158
Database
ISI
SICI code
0366-7022(1998):2<157:RSEBFA>2.0.ZU;2-A
Abstract
The reaction of functionalized fluorobenzenes, such as fluoroacetophen ones and (fluorophenyl) oxazolines, with Me3SiSiMe3 in the presence of a catalytic amount of a rhodium complex results in a site-selective S i-F exchange to give ortho(trimethylsilyl)fluorobenzenes. The reaction involves cleavage of C-F bonds.