CROWN ETHER-HALF-CAPPED SODIUM-IONS AS BRIDGES IN THE FORMATION OF COMPLEX POLYMER, STRUCTURE OF [((BENZO-15-CROWN-5)NA)(2)PD(I-MNT)(2)](N)(I-MNT = [S2C=C(CN)(2)](2-))
Dl. Long et al., CROWN ETHER-HALF-CAPPED SODIUM-IONS AS BRIDGES IN THE FORMATION OF COMPLEX POLYMER, STRUCTURE OF [((BENZO-15-CROWN-5)NA)(2)PD(I-MNT)(2)](N)(I-MNT = [S2C=C(CN)(2)](2-)), Chemistry Letters, (2), 1998, pp. 171-172
The reaction of Na2Pd(i-mnt)(2) and benzo-15-crown-5 leads to an unpre
cedented infinite chain-like [{(benzo-15-crown-5)Na}(2) Pd(i-mnt)(2)](
n), in which the conjugated species Pd(i-mnt)(2) are linked by crown e
ther-half capp ed sodium ions via Na-NC bonds.