CORRELATION OF THE FRONTIER ORBITAL PROPERTIES OF ALKANOLAMINES WITH THE EXPERIMENTAL CO2 LOADING

Authors
SUDA T ZHANG Y IWAKI T NOMURA M
Citation
T. Suda et al., CORRELATION OF THE FRONTIER ORBITAL PROPERTIES OF ALKANOLAMINES WITH THE EXPERIMENTAL CO2 LOADING, Chemistry Letters, (2), 1998, pp. 189-190
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
2
Year of publication
1998
Pages
189 - 190
Database
ISI
SICI code
0366-7022(1998):2<189:COTFOP>2.0.ZU;2-J
Abstract
The HOMO energy and the superdelocalizability for the most stable conf ormation of 18 kinds of alkanolamines plotted against experimentally m easured absorption loading of CO2 in an aqueous amine solution showed a good linear relationship for the usual secondary and tertiary amines , indicating that the frontier orbital properties of these amines appe ar to be predominant for the amine-CO2 reaction.