AN ANALYTICAL FORM DESCRIBING T-2 DISPERSIONS RESULTING FROM DIFFUSIVE EXCHANGE

Citation
Mak. Williams et Tk. Halstead, AN ANALYTICAL FORM DESCRIBING T-2 DISPERSIONS RESULTING FROM DIFFUSIVE EXCHANGE, Molecular physics, 93(4), 1998, pp. 609-613
Citations number
19
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00268976
Volume
93
Issue
4
Year of publication
1998
Pages
609 - 613
Database
ISI
SICI code
0026-8976(1998)93:4<609:AAFDTD>2.0.ZU;2-9
Abstract
Dispersions in the H-1 T-2 (Carr-Purcell-Meiboom-Gill) relaxation beha viour analogous to those well known to result from chemical exchange h ave been generated by numerical simulations of fast diffusive exchange between two spatially resolved regions having distinct NMR parameters . These resultant curves have been successfully fitted to a Carver-Ric hards functional form. Hence, apparent exchange rates and geometry-dep endent scaling factors of the frequency difference between regions hav e been extracted, which allow dispersions arising from spatially heter ogeneous systems to be described by a two-site exchange model.