This review describes the recent development of membrane reactors for
biological treatment of waste gases. In this type of bioreactor gaseou
s pollutants are transferred through a membrane to the liquid phase, w
here micro-organisms degrade the pollutants. The membrane bioreactor c
ombines the advantages of membrane devices with the clean technology o
f biological air purification. Two types of membrane materials can be
used for gas-liquid contact: hydrophobic microporous material and dens
e material, such as silicone rubber. Microporous material generally ha
s a higher permeability, but dense membranes can be advantageous in th
e case specific selectivity is required. Biomass is generally present
as a biofilm on the membrane, but may also be suspended in the liquid
phase. In a number of cases the reactor performance appears to be hamp
ered by an unstable biofilm performance and/or by clogging of the liqu
id channels due to excess biomass formation. So far: membrane bioreact
ors for waste gas treatment have only been tested on laboratory scale.
If the long-term stability of these reactors can be demonstrated, we
expect membrane bioreactors to be useful tools in the treatment of gas
streams containing poorly water-soluble pollutants and highly chlorin
ated hydrocarbons, which are difficult to treat with the conventional
methods for biofiltration. (C) 1998 Elsevier Science B.V.