The role of ozone in absorbing ultraviolet solar radiation is well kno
wn, Ozone also makes a significant contribution to the radiative balan
ce of the upper troposphere and lower stratosphere, such that changes
in the distribution of ozone in these atmospheric regions will affect
the radiative forcing of climate(1,2). Furthermore, tropospheric ozone
is the source of the hydroxyl radical which controls the abundance an
d distribution of many atmospheric constituents, including greenhouse
gases such as methane and hydrochlorofluorocarbons, Tropospheric ozone
is produced photochemically in situ and is also transported down from
the stratosphere, but the relative importance of these two sources to
its global budget is poorly understood, High-quality tropospheric and
lower-stratospheric ozone profile measurements are available from son
des and lidar techniques, but their geographical sampling is very limi
ted. Complementary satellite measurements of the global ozone distribu
tion in this height region are therefore required to quantify ozone's
tropospheric budget and its participation in climate-forcing and tropo
spheric chemistry. Here we present direct measurements of tropospheric
ozone concentrations from space, made by the European Space Agency's
Global Ozone Monitoring Experiment. These results demonstrate the pote
ntial of satellite measurements to provide self-consistent tropospheri
c and stratospheric ozone distributions on a global scale.