CALORIMETRY OF YTTRIUM TRIHALIDES AND YTT RIUM OXYHALIDES

Authors
OPPERMANN H EHRLICH S HENNIG C
Citation
H. Oppermann et al., CALORIMETRY OF YTTRIUM TRIHALIDES AND YTT RIUM OXYHALIDES, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 52(3), 1997, pp. 305-310
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
52
Issue
3
Year of publication
1997
Pages
305 - 310
Database
ISI
SICI code
0932-0776(1997)52:3<305:COYTAY>2.0.ZU;2-#
Abstract
The heats of solution of Yttrium, YOCL, YOBr, YOI, YCl3, YBr3, YI3 and Y2O3 were determined in 4n HX. From those the enthalpies of formation of Yttrium Trihalides YX3 and Yttrium Oxyhalides YOX at 298 K were de rived: Delta(B)(0)(YCl3,f,298) = -240.4 +/- 0.6 kcal/mol, Delta H-B(0) (YBr3,f,298) = -202.1 +/- 1.5 kcal/mol, Delta H-B(0)(YI3,f,298) = -147 .0 +/- 1.7 kcal/mol, Delta H-B(0)(YOClf,298) = -240.2 +/- 1.0 kcal/mol , Delta H-B(0)(YOBrf,298) = -229.7 +/- 2.0 kcal/mol, Delta H-B(0)(YOIf ,298) = -208.8 +/- 2.0 kcal/mol.