SYNTHESES AND STRUCTURE OF POTASSIUM-4,4- IFLUORO-[1,3,2]DITHIAZETIDINIDE-1,1,3,3-TETRAOXIDE AND AFLUORO-[1,3,2]DITHIAZOLIDINIDE-1,1,3,3-TETRAOXIDE

Authors
JUSCHKE R HENKEL G SARTORI P
Citation
R. Juschke et al., SYNTHESES AND STRUCTURE OF POTASSIUM-4,4- IFLUORO-[1,3,2]DITHIAZETIDINIDE-1,1,3,3-TETRAOXIDE AND AFLUORO-[1,3,2]DITHIAZOLIDINIDE-1,1,3,3-TETRAOXIDE, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 52(3), 1997, pp. 359-366
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
52
Issue
3
Year of publication
1997
Pages
359 - 366
Database
ISI
SICI code
0932-0776(1997)52:3<359:SASOPI>2.0.ZU;2-N
Abstract
Reactions of perfluoroalkane-1,n-bis(sulfonylfluorides) (n = 1-2) (1-2 ) with liquid ammonia in tetrahydrofuran (THF) lead to the cyclic ammo nium imides 3-4. These cyclic imides 3-4 can easily be transformed to other salts using the corresponding hydroxides. X-ray structure analys es (T = 150 K) were performed for the potassium ifluoro-[1,3,2]dithiaz etidinide-1,1,3,3-tetraoxide 5 and afluoro-[1,3,2]dithiazetidinide-1,1 ,3,3-tetraoxide 6. Cylic imides of the type 3, 5 have not been reporte d previously. Their formation and their nmr-data are discussed.