The electronic structure of the Kondo insulator Ce3Bi4Pt3 has been stu
died by high-resolution photoelectron spectroscopy. Indications of the
unusual electronic structure are observed: the 4f derived peak near t
he Fermi level is located at a binding energy of 20 meV and is not cut
-off by the Fermi edge as in conventional Kondo systems; for low photo
n energies, where the 4f contribution is negligible and the conduction
band states are probed, a loss of spectral intensity in the same ener
gy range is observed. These observations are related to the opening of
a gap at low temperature, confirming the picture that hybridisation b
etween a localised 4f state and the conduction band is responsible for
the insulating character of this material.