Three series of ferroelectric liquid crystals have been synthesized, h
aving three ester groups in the mesogenic core and one ester group in
the chiral chain. The ester groups introduced into the core decrease t
he temperature of crystallization, which results in a broad temperatur
e range ferroelectric smectic C phase in homologues with a long non-ch
iral chain. These phases exhibit a high spontaneous polarization and r
elatively short pitch of the helical structure.