In order to investigate the symmetry (i.e. sphericity) of donor-bound
electron wavefunctions in quantum wells, we have invoked a two-paramet
er trial wavefunction. One parameter is the Bohr radius lambda, whilst
the other is the eccentricity parameter zeta. The latter incorporates
the effect of the quantum well (QW) on the carrier motion in the grow
th (i.e. the z) direction. Working within the envelope function approx
imation it is shown that the donor wavefunction has the form of a prol
ate spheroid. However, calculations of the ratio lambda/zeta shows tha
t it is the value of lambda which determines the essential symmetry of
the wavefunction. (C) 1998 Academic Press Limited.