BIOTRANSFORMATIONS XLII - APPLES AS ENANTIOSPECIFIC BIOREAGENTS IN THE HYDROLYSIS OF RACEMIC ESTERS AND OXYGENATION OF ALCOHOLS OBTAINED DURING THE PROCESS
A. Mironowicz, BIOTRANSFORMATIONS XLII - APPLES AS ENANTIOSPECIFIC BIOREAGENTS IN THE HYDROLYSIS OF RACEMIC ESTERS AND OXYGENATION OF ALCOHOLS OBTAINED DURING THE PROCESS, Acta Societatis Botanicorum Poloniae, 66(3-4), 1997, pp. 325-328
Biotransformation carried out by apples (Malus silvestris) resulted in
enantiospecific hydrolysis of racemic acetates, the derivatives of se
condary aromatic-aliphatic or terpenic alcohols. The alcohols are oxyg
enated to ketones (reversible reaction). The differences in the rate o
f the hydrolysis of enantiomeric esters enable isolation of pure, unre
acted R-acetates.