BIOTRANSFORMATIONS XLII - APPLES AS ENANTIOSPECIFIC BIOREAGENTS IN THE HYDROLYSIS OF RACEMIC ESTERS AND OXYGENATION OF ALCOHOLS OBTAINED DURING THE PROCESS

Authors
Citation
A. Mironowicz, BIOTRANSFORMATIONS XLII - APPLES AS ENANTIOSPECIFIC BIOREAGENTS IN THE HYDROLYSIS OF RACEMIC ESTERS AND OXYGENATION OF ALCOHOLS OBTAINED DURING THE PROCESS, Acta Societatis Botanicorum Poloniae, 66(3-4), 1997, pp. 325-328
Citations number
9
ISSN journal
00016977
Volume
66
Issue
3-4
Year of publication
1997
Pages
325 - 328
Database
ISI
SICI code
0001-6977(1997)66:3-4<325:BX-AAE>2.0.ZU;2-C
Abstract
Biotransformation carried out by apples (Malus silvestris) resulted in enantiospecific hydrolysis of racemic acetates, the derivatives of se condary aromatic-aliphatic or terpenic alcohols. The alcohols are oxyg enated to ketones (reversible reaction). The differences in the rate o f the hydrolysis of enantiomeric esters enable isolation of pure, unre acted R-acetates.