A graphical procedure based on residue-curve maps and distillation-lin
e maps is developed for the synthesis of sequences of distillation col
umns for homogeneous azeotropic distillation. The feasibility of separ
ation is determined by the overlap of product operation leaves defined
as the feasible region containing all column profiles that lead to a
desired product specification, which need not be a precise composition
. Column sections may be constrained to operate within a subregion of
the composition space, in which case the limit of operation is defined
as a section boundary. Section boundaries for node-type and saddle-ty
pe products are established, and it is shown that they do not always c
oincide with simple-distillation or distillation-line boundaries. When
the distillation line (or residue curve) and pinch-point curve from a
desired product terminate at different nodes in the composition space
, then distillation sequences using complex column arrangements can be
proposed.