Tj. Wang et al., SILICA-SUPPORTED METHYLTRIOXORHENIUM COMPLEX OF GAMMA-(2,2'-DIPYRIDYL)-AMINO-PROPYLPOLYSILOXANE AS A NOVEL CATALYST FOR EPOXIDATION OF ALKENES, Journal of macromolecular science. Pure and applied chemistry, A35(3), 1998, pp. 531-538
Silica supported methyltrioxorhenium complex of gamma-(2,2'-dipyridyl)
-aminopropyl polysiloxane (III) has been synthesized and demonstrated
as a novel catalyst of high activity, stability and improved selectivi
ty for epoxidation of alkenes with hydrogen peroxide at room temperatu
re. The catalyst can be recycled at least five times.